[2] The Twenty Amino Acids of Proteins

From: Subject: =?iso-8859-1?Q?=5B2=5D_The_Twenty?= =?iso-8859-1?Q?_Amino_Acids_o?= =?iso-8859-1?Q?f_Proteins?= Date: Wed, 21 Jan 2004 14:27:02 -0500 MIME-Version: 1.0 Content-Type: multipart/related; boundary="----=_NextPart_000_00D4_01C3E02A.A2DCBF50"; type="text/html" X-MimeOLE: Produced By Microsoft MimeOLE V5.00.3314.1001 This is a multi-part message in MIME format. ------=_NextPart_000_00D4_01C3E02A.A2DCBF50 Content-Type: text/html; charset="iso-8859-1" Content-Transfer-Encoding: quoted-printable Content-Location: =?iso-8859-1?B?aHR0cDovL3d3dy53ZWI=?= =?iso-8859-1?B?LWJvb2tzLmNvbS9Nb0I=?= =?iso-8859-1?B?aW8vRnJlZS9DaDJBMi4=?= =?iso-8859-1?B?aHRt?= [2] The Twenty Amino Acids of Proteins

MoBio Contents =	The = Twenty Amino=20 Acids of Proteins
Chapter=20 2	A \| B \| C \| D \| E \| F \| G

Based on the physicochemical properties of R groups, the 20 = amino acids=20 of proteins may be classified as follows.

1. Acidic: including aspartic acid = (aspartate) and glutamatic acid (glutamate). In a neutral = solution,=20 the R group of an acidic amino acid may lose a proton and become=20 negatively charged.

2. Basic: including lysine, = arginine and=20 histidine. In a neutral solution, the R group of a basic = amino acid=20 may gain a proton and become positively charged. Interaction = between=20 positive and negative R groups may form a salt bridge, = which is an=20 important stabilizing force in proteins.

3. Aromatic: including tyrosine, = tryptophan=20 and phenylalanine. Their R groups contain an aromatic=20 ring.

4. Sulfur: including cysteine and=20 methionine. Their R groups contain a sulfur atom (S). The disulfide = bond=20 formed between two cysteine residues provides a strong = force for=20 stabilizing the globular structure. A unique feature about=20 methionine is that the synthesis of all peptide = chains=20 starts from methionine (Chapter 5 = Section=20 C).

5. Uncharged hydrophilic: = including serine,=20 threonine, asparagine and glutamine. Their R groups are = hydrophilic=20 and capable of forming hydrogen bonds.

6. Inactive hydrophobic: including = glycine,=20 alanine, valine, leucine and isoleucine. These amino acids = are more=20 likely to be buried in the protein interior. Their R groups = do not=20 form hydrogen bonds and rarely participate in chemical = reactions.

7. Special structure: including=20 proline. In most amino acids, the R group and the amino = group are=20 not directly connected. Proline is the only exception among = 20 amino=20 acids found in protein. Due to this special feature, proline = is=20 often located at the turn of a peptide chain in the = three-dimensional=20 structure of a protein.

Figure 2-A-2. Names, symbols, chemical = structures and=20 hydrophobicity indices of the 20 amino acids found in = proteins. They=20 are arranged in the order as discussed above.

=20

Note: The hydrophobicity index tells the relative = hydrophobicity=20 among amino acids. More positive value indicates stronger=20 hydrophobicity. Hydrophilic amino acids have negative = values. =20 In a protein, hydrophobic amino acids are more likely to be = located in the=20 protein interior, whereas hydrophilic amino acids are more likely = to face=20 the aqueous environment.

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